A High-efficiency Cathode Using Co₃O₄ and Carbon Paper by Electrodeposition for Rechargeable Lithium-oxygen Batteries

The conductivity, microstructure, low cost, eco-friendliness, simple and controllable preparation are key points of the preparation and application of cathode materials for lithium-oxygen batteries. Considering the above-mentioned important factors comprehensively, the Co₃O₄@CP electrode with a three-dimensional structure was prepared by directly growing Co₃O₄ on the surface of carbon paper (CP) using a simple and controllable electrodeposition method. The obtained Co₃O₄ depositing layer has a nanosheet microstructure and can provide abundant catalytic active sites for the oxygen evolution and reduction reactions. The network architecture of electronic transmission is constructed by CP in the cathode, promoting the efficiency of the electrode reaction. It’s worth noting that the binder-free and conductive additive-free cathode is beneficial to reduce side reactions. The lithium-oxygen battery assembled with the obtained Co₃O₄@CP electrode showed satisfactory electrochemical performance. The cell assembled with the obtained Co₃O₄@CP electrode provided a discharge specific capacity of 10954.7 mA·h·g⁻¹ at a current density of 200 mA·g⁻¹, and the voltage profiles of the cell were good under 100 mA·g⁻¹ at a limited capacity of 500 mA·h g⁻¹ based on the mass of Co₃O₄. Therefore, the Co₃O₄@CP composite material is a promising candidate with good application prospects as a cathode material for lithium-oxygen batteries.